Two complexes [Fe(1,10-phen)₂Ni(CN)₄]_n (1), {[Fe₂(1,10-phen)₄(CN)₄Co₂(1,10-phen)₂Fe(CN)₆]·2H₂O}_n (2) were prepared in the reaction of K₃[Fe(CN)₆] as cyanometalate anions with different metal cations such as Co²⁺ or Ni²⁺ under hydrothermal conditions in the presence of 1,10-phenanthroline (1,10-phen). The X-ray crystallographic studies suggested that the two cations Fe²⁺ and Ni²⁺ are alternately bridged by the cyanide ligands to form a 1D zigzag chain with 1,10-phen terminal ligands in complex 1. While the cyanide groups bridge Fe²⁺ and Co²⁺ ions form step-like chain constituted by pentanuclear structural unit [Fe₂(1,10-phen)₄(CN)₄Co₂(1,10-phen)₂Fe(CN)₆] in complex 2. It had been found that the structures of these complexes are metal ion dependent. The magnetic behavior of complexes 1 and 2 was studied and the nature of the magnetic interactions could not be adequately fit to several different models. Antiferromagnetic interactions appear to dominate in complex 1, and complex 2 is complicated by the orbital contribution to the magnetic susceptibility from the anisotropic Co²⁺ ion.

两种络合物[Fe（1,10-phen）₂ Ni（CN）₄ ] _n（1），{[Fe ₂（1,10-phen）₄（CN）₄ Co ₂（1,10-phen）₂ Fe （CN）₆ ]·2H ₂ O} _n（2）是在水热条件下，在水热条件下，将K ₃ [Fe（CN）₆ ]作为氰基金属酸盐阴离子与不同的金属阳离子（例如Co ²⁺或Ni ²⁺）反应制备的。 1,10-菲咯啉（1,10-phen）的存在。X射线晶体学研究表明，两个阳离子Fe ²⁺和Ni²⁺由氰化物配体交替桥连，形成1D锯齿形链，在复合物1中具有1,10-phen末端配体。氰化物基团桥接Fe ²⁺和Co ²⁺离子形成由五核结构单元[Fe ₂（1,10-phen）₄（CN）₄ Co ₂（1,10-phen）₂ Fe（ CN）₆ ]在络合物2中。已经发现这些络合物的结构是金属离子依赖性的。配合物1和2的磁行为进行了研究，但电磁相互作用的性质无法完全适合几种不同的模型。反铁磁相互作用似乎在复合物1中占主导地位，而复合物2由于各向异性Co ²⁺离子对磁化率的轨道贡献而变得复杂。