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Syntheses, crystal structures and magnetic properties of two new cyano-bridged bimetallic complexes

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Abstract

Two complexes [Fe(1,10-phen)2Ni(CN)4]n (1), {[Fe2(1,10-phen)4(CN)4Co2(1,10-phen)2Fe(CN)6]·2H2O}n (2) were prepared in the reaction of K3[Fe(CN)6] as cyanometalate anions with different metal cations such as Co2+ or Ni2+ under hydrothermal conditions in the presence of 1,10-phenanthroline (1,10-phen). The X-ray crystallographic studies suggested that the two cations Fe2+ and Ni2+ are alternately bridged by the cyanide ligands to form a 1D zigzag chain with 1,10-phen terminal ligands in complex 1. While the cyanide groups bridge Fe2+ and Co2+ ions form step-like chain constituted by pentanuclear structural unit [Fe2(1,10-phen)4(CN)4Co2(1,10-phen)2Fe(CN)6] in complex 2. It had been found that the structures of these complexes are metal ion dependent. The magnetic behavior of complexes 1 and 2 was studied and the nature of the magnetic interactions could not be adequately fit to several different models. Antiferromagnetic interactions appear to dominate in complex 1, and complex 2 is complicated by the orbital contribution to the magnetic susceptibility from the anisotropic Co2+ ion.

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Acknowledgements

Thanks are due to the Fundamental Research Fund for the Heilongjiang Provincial Universities (1355ZD001, 1353MSYQN004) and the Mudanjiang Normal University Key Project (GP2018002).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Mu Danjiang Normal University, Mu Danjiang, 157012, People’s Republic of China

    Shuxin Cui, Baili Zhu, Shuanglong Xiang, Pengzhen He, Qianzhu Yin & Minghui Zuo

  2. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Xiaoying Zhang

  3. College of Mathematics, Jilin Normal University, Siping, 136000, People’s Republic of China

    Bo Xu

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  1. Shuxin Cui
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Cui, S., Zhu, B., Zhang, X. et al. Syntheses, crystal structures and magnetic properties of two new cyano-bridged bimetallic complexes. Transit Met Chem 46, 345–351 (2021). https://doi.org/10.1007/s11243-021-00451-x

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