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Investigation of structural, optical, and magnetic properties of Co 2+ ions substituted CuFe 2 O 4 spinel ferrite nanoparticles prepared via precipitation approach
Journal of the Australian Ceramic Society ( IF 1.8 ) Pub Date : 2021-01-14 , DOI: 10.1007/s41779-020-00556-z
Talaat M. Hammad , S. Kuhn , Ayman Abu Amsha , R. Hempelmann

Nanoparticles of undoped and cobalt-doped copper ferrite Cu1-xCoxFe2O4 (x = 0.2, 0.4, 0.6, 0.8, and 1.0) were successfully synthesized by a co-precipitation method. The influence of Co2+ substitutions on the structure, morphological, optical, and magnetic properties of Cu1-xCoxFe2O4 nanoferrites was studied. The crystallite size found by XRD increased from ∼ 10 to∼ 25 nm. The lattice parameter increased from 8.332 to 8.371 Å with increasing the Co2+ content. The FTIR spectra of Cu1-xCoxFe2O4 display two strong absorption bands in the range of 400–200 cm−1. The band gap energy of nanoferrites is found to decrease from 3.65 to 3.20 eV with an increase in the content of Co2+ ions. It has been observed that the luminescence intensity decreases in copper ferrite matrices with an increase in the ratio of Co2+. The results show the magnetic properties of copper ferrite are significantly affected by the doping amount of Co2+ ions. The saturation magnetization increases with increasing cobalt ion concentration as indicated in the M-H loops.



中文翻译:

沉淀法制备Co 2+离子取代的CuFe 2 O 4尖晶石铁氧体纳米粒子的结构,光学和磁性

 通过共沉淀法成功地合成了未掺杂和掺杂钴的铜铁氧体Cu 1- x Co x Fe 2 O 4x = 0.2、0.4、0.6、0.8和1.0)的纳米粒子。研究了Co 2+取代对Cu 1- x Co x Fe 2 O 4纳米铁氧体的结构,形貌,光学和磁性的影响。通过XRD发现的微晶尺寸从〜10增加到〜25nm。随着Co 2+含量的增加,晶格参数从8.332增加到8.371Å 。Cu 1- x Co的FTIR光谱x Fe 2 O 4在400–200 cm -1范围内显示两个强吸收带。发现随着Co 2+离子含量的增加,纳米铁氧体的带隙能从3.65 eV降低到3.20 eV。已经观察到,随着Co 2+比率的增加,铜铁氧体基质中的发光强度降低。结果表明,Co 2+离子的掺杂量显着影响铜铁氧体的磁性。如MH回路所示,饱和磁化强度随着钴离子浓度的增加而增加。

更新日期:2021-01-14
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