Nowadays, the processing of bio-renewable raw materials into biofuels and valuable products, namely, bifunctional carbonyl/carboxyl compounds, which serve as the basis for biopolymers, has become one of the most important areas in the development of heterogeneous catalysis. The present review discusses the most recent results in the field of synthesis of valuable products via the oxidative conversion of platform molecules such as glycerol, 5-hydroxymethylfurfural, and 1,2-propanediol using heterogeneous catalytic systems. Together with traditional catalysts based on gold and bimetallic Au–Pt nanoparticles, catalysts based on transition metal oxides and their compositions are being considered. This review observes the trends in the development of catalytic systems that allow bifunctional carbonyl/carboxyl compounds to be obtained, including systems based on metal–organic framework polymers with immobilized redox active sites comprising clusters of noble metals or bimetallic materials. The subsequent development of these catalytic materials has currently attracted increasing attention from the scientific community.

中文翻译：

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生物纳米平台分子及其转化产物在金属纳米粒子催化剂上的选择性氧化：综述

如今，将生物可再生原料加工为生物燃料和有价值的产品，即作为生物聚合物基础的双官能羰基/羧基化合物，已成为非均相催化发展中最重要的领域之一。本评论讨论了通过合成有价值的产品领域的最新成果使用非均相催化系统对平台分子（例如甘油，5-羟甲基糠醛和1,2-丙二醇）的氧化转化。与基于金和双金属Au-Pt纳米粒子的传统催化剂一起，正在考虑基于过渡金属氧化物及其组成的催化剂。这篇综述观察了催化体系发展的趋势，该体系允许获得双官能的羰基/羧基化合物，包括基于金属有机骨架聚合物的体系，该体系具有固定的氧化还原活性位，包括贵金属或双金属材料簇。这些催化材料的后续开发目前引起了科学界的越来越多的关注。