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Super ductility in HDPE/EVA blends triggered by synthetic amorphous nanotalc
Journal of Polymer Research ( IF 2.8 ) Pub Date : 2021-01-05 , DOI: 10.1007/s10965-020-02389-7
Giovanni Savini , Rodrigo L. Oréfice

Binary and ternary systems of HDPE/EVA with amorphous nanotalc contents of 1% m/m were prepared by mixing the components in the molten state in a twin-screw extruder followed by injection molding. The thermal properties were investigated by thermogravimetric analysis (TGA) and by differential scanning calorimetry (DSC) and showed that the thermal stability of the nanocomposites was slightly improved with nanotalc incorporation. The morphology of the nanocomposites, investigated by scanning electron microscopy (SEM), revealed a good dispersion of the nanotalc layers within the polymer matrix, and changes of the morphology from sea-island to co-continuous as a function of the composition, as well as refinement of the size of EVA phase. The dynamic mechanical properties of the samples showed that the storage modulus increased with a diffuse pattern with the addition of the nanotalc, while the tan δ curve showed an intense peak for the 50EVA/NTA nanocomposite at the Tg of EVA. The mechanical properties of nanocomposites were studied by tensile and impact tests. A remarkable behavior was verified for the 50EVA/NTA nanocomposite, which manifested a characteristic of super ductility and high damping capacity, showing that the amorphous nanotalc can be used as a high-performance filler to improve the ductility of polymeric systems.



中文翻译:

合成无定形纳米滑石在HDPE / EVA共混物中具有超强延展性

通过在双螺杆挤出机中混合熔融态的组分,然后注塑,制备了具有1%m / m非晶态纳米滑石含量的HDPE / EVA二元和三元体系。通过热重分析(TGA)和差示扫描量热法(DSC)研究了热性能,结果表明,掺入纳米滑石可稍微改善纳米复合材料的热稳定性。通过扫描电子显微镜(SEM)研究的纳米复合材料的形貌揭示了纳米滑石层在聚合物基质中的良好分散性,以及从岛状到共连续形貌的形态变化也随组成的变化而变化。作为EVA相尺寸的细化。样品的动态力学性能表明,随着纳米滑石的添加,储能模量以扩散模式增加,而tanδ曲线显示了在EVA的Tg处50EVA / NTA纳米复合材料的强烈峰。通过拉伸和冲击试验研究了纳米复合材料的机械性能。验证了50EVA / NTA纳米复合材料的显着行为,该行为表现出超延展性和高阻尼能力的特征,表明无定形纳米滑石可以用作高性能填料,以提高聚合物体系的延展性。

更新日期:2021-01-05
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