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Peculiarities of Intermetallic Phase Formation in the Process of a Solid State Reaction in (Al/Cu) n Multilayer Thin Films
JOM ( IF 2.1 ) Pub Date : 2021-01-04 , DOI: 10.1007/s11837-020-04522-9
Evgeny T. Moiseenko , Sergey M. Zharkov , Roman R. Altunin , Oleg V. Belousov , Leonid A. Solovyov , Vladimir V. Yumashev , Mikhail N. Volochaev , Galina M. Zeer

Phase formation in a solid state reaction in Al/Cu bilayer and multilayer thin films was studied by the methods of in situ transmission electron microscopy, electron diffraction, simultaneous thermal analysis and x-ray diffraction. It was established that the phase formation sequences in the (Al/Cu)n (n = 2, 15) multilayer thin films (θ-Al2Cu → γ1-Al4Cu9 → η2-AlCu) and Al/Cu bilayer thin films (θ-Al2Cu → η2-AlCu → γ1-Al4Cu9) were different. It was assumed that the phase formation process in the thin films was strongly affected by a number of copper/aluminum interfaces due to the changes of aluminum and copper diffusion current.



中文翻译:

(Al / Cu)n多层薄膜中固态反应过程中金属间相形成的特殊性

通过原位透射电子显微镜,电子衍射,同时热分析和X射线衍射等方法研究了Al / Cu双层和多层薄膜在固态反应中的相形成。它建立在(铝/铜)相形成序列ÑÑ  = 2,15)的多层薄膜(θ-Al系2铜→γ 1 -Al 4的Cu 9  →η 2 -AlCu)和铝/铜双层薄膜(θ-Al系2的Cu→η 2 -AlCu→γ 1 -Al 4的Cu 9)是不同的。假定由于铝和铜扩散电流的变化,薄膜中的相形成过程受到许多铜/铝界面的强烈影响。

更新日期:2021-01-05
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