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CATION AND ANION SUBLATTICES IN A SERIES OF TYPICAL CRISTAL STRUCTURES
Journal of Structural Chemistry ( IF 0.8 ) Pub Date : 2020-10-01 , DOI: 10.1134/s0022476620100108
S. V. Borisov , S. A. Magarill , N. V. Pervukhina

The crystallographic analysis of Rb2NaAlF6\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(Fd\bar{3}m)$$\end{document} and (Al,V)4(P4O12)3\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(I\bar{4}3d)$$\end{document} cubic structures and the trigonal structure of phenakite Be2SiO4 \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(R\bar{3})$$\end{document} is performed. In Rb2NaAlF6 a large and heavy Rb cation stabilizes cation and anion sublattices, promoting their maximum symmetry. In the structure of cyclic tetraphosphate, the core is formed by the cation sublattice with a noticeable deviation of P cations from its nodes. The anion arrangement ordered by pseudo-cubic and hexagonal sublattices with pseudo-symmetry features dominates in the trigonal structure of phenakite.

中文翻译:

一系列典型晶体结构中的阳离子和阴离子亚晶格

V)4(P4O12)3\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(I\bar{4}3d)$$\end{document} 立方结构和 phenakite Be2SiO4 的三角结构 \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$(R\bar{3})$$\end{document} 被执行。在 Rb2NaAlF6 中,一个大而重的 Rb 阳离子稳定了阳离子和阴离子亚晶格,促进了它们的最大对称性。在环状四磷酸的结构中,核心由阳离子亚晶格形成,P 阳离子与其节点有明显的偏差。由具有伪对称特征的伪立方和六边形亚晶格有序排列的阴离子排列在吩克石的三角结构中占主导地位。
更新日期:2020-10-01
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