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CATION AND ANION SUBLATTICES IN A SERIES OF TYPICAL CRISTAL STRUCTURES

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Abstract

The crystallographic analysis of Rb2NaAlF6 \((Fd\bar{3}m)\) and (Al,V)4(P4O12)3 \((I\bar{4}3d)\) cubic structures and the trigonal structure of phenakite Be2SiO4 \((R\bar{3})\) is performed. In Rb2NaAlF6 a large and heavy Rb cation stabilizes cation and anion sublattices, promoting their maximum symmetry. In the structure of cyclic tetraphosphate, the core is formed by the cation sublattice with a noticeable deviation of P cations from its nodes. The anion arrangement ordered by pseudo-cubic and hexagonal sublattices with pseudo-symmetry features dominates in the trigonal structure of phenakite.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Borisov, S. A. Magarill & N. V. Pervukhina

  2. Novosibirsk State University, Novosibirsk, Russia

    N. V. Pervukhina

Authors
  1. S. V. Borisov
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  2. S. A. Magarill
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  3. N. V. Pervukhina
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Correspondence to S. V. Borisov.

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Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. CATION AND ANION SUBLATTICES IN A SERIES OF TYPICAL CRISTAL STRUCTURES. J Struct Chem 61, 1585–1593 (2020). https://doi.org/10.1134/S0022476620100108

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