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Chemiluminescence in the Auto-Oxidation of Luminol in Dimethyl Sulfoxide: Kinetic Effects of Alkalis, Quenching by Nitroblue Tetrazolium, and Elimination of Quenching by Hydrogen Peroxide
Russian Journal of Physical Chemistry A ( IF 0.7 ) Pub Date : 2020-10-30 , DOI: 10.1134/S0036024420110308
Yu. B. Tsaplev , A. V. Trofimov

Conditions and ways of inhibiting, quenching, and subsequently restoring the chemiluminescence of luminol in alkaline aerated dimethyl sulfoxide are determined. Data are obtained that testify to the key role of electron transfer from luminol dianions to oxygen in the auto-oxidation and chemiluminescence of luminol under these conditions.

中文翻译:

鲁米诺在二甲基亚砜中的自氧化过程中的化学发光:碱的动力学效应,硝基蓝四氮唑的猝灭和过氧化氢的猝灭

确定了在碱性充气二甲基亚砜中抑制,淬灭和随后恢复鲁米诺化学发光的条件和方法。获得的数据证明了在这些条件下电子从鲁米诺双阴离子向氧的转移在鲁米诺的自动氧化和化学发光中的关键作用。
更新日期:2020-10-30
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