Abstract
Conditions and ways of inhibiting, quenching, and subsequently restoring the chemiluminescence of luminol in alkaline aerated dimethyl sulfoxide are determined. Data are obtained that testify to the key role of electron transfer from luminol dianions to oxygen in the auto-oxidation and chemiluminescence of luminol under these conditions.
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Notes
Since the constant of hydration of the hydroxide ion exceeds 1600 M−1, a water molecule also accompanies the free (not participating in an ion pair) hydroxide ion.
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Funding
This work was supported by the Russian Foundation for Basic Research, project no. 19-53-18019_Bolg_a.
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Translated by V. Glyanchenko
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Tsaplev, Y.B., Trofimov, A.V. Chemiluminescence in the Auto-Oxidation of Luminol in Dimethyl Sulfoxide: Kinetic Effects of Alkalis, Quenching by Nitroblue Tetrazolium, and Elimination of Quenching by Hydrogen Peroxide. Russ. J. Phys. Chem. 94, 2369–2374 (2020). https://doi.org/10.1134/S0036024420110308
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DOI: https://doi.org/10.1134/S0036024420110308