Persulfurated aromatic molecules, namely, persulfurated arenes, have been concerned in the field of organic synthesis, supramolecular chemistry, and electrocatalysis for decades. However, the luminescent properties of persulfurated arenes have long been underestimated. In recent years, follow-up observations reveal the mysterious shades of the aggregate-induced phosphorescence (AIP) feature of these compounds. Then, the AIP feature has received considerable attention afterwards. Till now, there is a growing trend of literatures that are dedicated to a further study of the AIP and a tunable fluorescence–phosphorescence complex emissive property of persulfurated arenes. Since this perspective is ignored in most other reviews in the relevant fields, herein, we aim to systematically review their development history of luminescent properties, shed light on their AIP and fluorescence–phosphorescence complex emissive property, and eventually try to conclude useful control ways to harness the attempting dual-emission nature.

数十年来，全硫酸化的芳族分子，即全硫化的芳烃，一直在有机合成，超分子化学和电催化领域中受到关注。然而，全硫化芳烃的发光特性长期以来被低估了。近年来，后续观察揭示了这些化合物的聚集体诱导的磷光（AIP）特征的神秘阴影。然后，AIP功能随后受到了相当大的关注。到目前为止，越来越多的文献致力于对AIP和全硫化芳烃的可调荧光-磷光复合发光特性进行研究。由于在相关领域的大多数其他评论中都忽略了这种观点，因此我们旨在系统地回顾其发光特性的发展历史，