Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(II) complex,Chemical Communications

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Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(II) complex
Chemical Communications ( IF 4.3 ) Pub Date : 2020-11-16 , DOI: 10.1039/d0cc06205g
Ryo Inoue _{1,

2,

3,

4,

5} , Riki Kondo _{1,

2,

3,

4,

5} , Yasuhiro Morisaki _{1,

2,

3,

4,

5}

Affiliation

An optically active binuclear platinum(II) complex based on planar chiral [2.2]paracyclophane was synthesized. The corresponding enantiomers exhibited red circularly polarized phosphorescence (CPP) with the dissymmetry factor |g_lum| = 1.0 × 10⁻³. We report, for the first time, theoretical estimation of the CPP |g_lum| value using relativistic calculations.

中文翻译：

[2.2]对环环烷基铂（II）配合物圆偏振磷光的实验和理论研究

合成了一种基于平面手性[2.2]对环环烷的旋光性双核铂（Ⅱ）配合物。相应的对映异构体显示红色圆偏振磷光（CPP），其不对称因子| 摹_LUM | ＝ 1.0×10 ^-3。我们首次报告了CPP的理论估算| 摹_LUM | 使用相对论计算的价值。

更新日期：2020-11-25

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