Issue 98, 2020

Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(ii) complex

Abstract

An optically active binuclear platinum(II) complex based on planar chiral [2.2]paracyclophane was synthesized. The corresponding enantiomers exhibited red circularly polarized phosphorescence (CPP) with the dissymmetry factor |glum| = 1.0 × 10−3. We report, for the first time, theoretical estimation of the CPP |glum| value using relativistic calculations.

Graphical abstract: Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
14 Sep 2020
Accepted
14 Nov 2020
First published
16 Nov 2020

Chem. Commun., 2020,56, 15438-15441

Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(II) complex

R. Inoue, R. Kondo and Y. Morisaki, Chem. Commun., 2020, 56, 15438 DOI: 10.1039/D0CC06205G

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