Abstract

This review deals with heterogeneous hydroformylation catalysts, specifically metal complexes fixed in an organic polymer structure. It describes the main catalyst synthesis methods, provides data on hydroformylation of unsaturated compounds (including asymmetric hydroformylation), and shows how those compounds can be used. The special focus is on the systematization of data on heterogeneous catalysts developed on the basis of porous organic polymers. Due to their porous structure, resistance to organic media and the high concentration of heteroatoms they contain, these materials can be considered promising for developing highly active, selective and stable heterogeneous catalysts for hydroformylation of unsaturated compounds, particularly higher linear olefins.

中文翻译：

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不饱和化合物加氢甲酰化反应中的聚合物非均相催化剂

摘要

这篇综述涉及非均相加氢甲酰化催化剂，特别是固定在有机聚合物结构中的金属络合物。它描述了主要的催化剂合成方法，提供了不饱和化合物加氢甲酰化的数据（包括不对称加氢甲酰化），并说明了如何使用这些化合物。特别关注基于多孔有机聚合物开发的非均相催化剂数据的系统化。由于它们的多孔结构，对有机介质的抵抗力以及它们所含的高浓度杂原子，这些材料被认为有望开发出用于不饱和化合物（尤其是高级直链烯烃）加氢甲酰化的高活性，选择性和稳定的多相催化剂。