Recent Developments in the Asymmetric Detrifluoroacetylative Reactions of in situ Generated Mono-Fluorinated Enolates,Current Organic Chemistry

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Recent Developments in the Asymmetric Detrifluoroacetylative Reactions of in situ Generated Mono-Fluorinated Enolates
Current Organic Chemistry ( IF 1.7 ) Pub Date : 2020-08-31 , DOI: 10.2174/1385272824999200801022712
Li Wang ₁ , Ziyi Li ₁ , Jiang Liu ₁ , Jianlin Han ₁ , Hiroki Moriwaki ₂ , Vadim A. Soloshonok ₃

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The development of an efficient and mild synthetic methodology for the construction of bioactive fluorine-containing molecules represents one of the hot research topics in general synthetic organic chemistry. In this review, some recent progresses achieved in the development of detrifluoroacetylatively generated mono-fluorinated enolates via CC bond cleavage and their asymmetric nucleophilic reactions for assembly of chiral quaternary C-F center containing compounds.

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