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Effects of Yttrium on the Microstructure and Corrosion Behavior of Pb-39Mg-10Al-1B-Y Alloys
Journal of Materials Engineering and Performance ( IF 2.2 ) Pub Date : 2020-11-17 , DOI: 10.1007/s11665-020-05317-4
Zhiqi Feng , Weizong Bao , Longke Bao , Mingjun Peng , Yonghua Duan

Pb-39Mg-10Al-1B-Y alloys with Y = 0, 0.2, 0.4, 0.6, 0.8, and 1.0 (wt.%) were fabricated by melting and casting. The microstructure and electrochemical corrosion behavior of the Pb-39Mg-10Al-1B-Y alloys in a 3.5 wt.% NaCl solution were investigated using x-ray diffraction, electron probe microanalysis, and scanning electron microscopy, polarization curve tests, electrochemical impedance spectroscopy (EIS), and electrochemical noise (EN). Mg2Pb + Pb eutectic gains are refined, and the distribution of Mg17Al12 + Mg eutectic gains becomes continuous by with the addition of Y. The polarization curves, EIS results and EN results show that the corrosion resistance of the alloys with various Y concentrations is in the order 0.8 > 1 > 0.6 > 0.4 > 0.2 > 0. The primary corrosion behaviors of Pb-39Mg-10Al-1B-Y alloys when Y ≤ 0.4 wt.% and Y > 0.4 wt.% are general corrosion and localized corrosion, respectively. There is a Mg-Mg2Pb galvanic cell present with Mg2Pb as the cathode and Mg as the anode. Moreover, Cl can accelerate the corrosion of the Mg phase.



中文翻译:

钇对Pb-39Mg-10Al-1B-Y合金的组织和腐蚀行为的影响

通过熔融和铸造制造具有Y = 0、0.2、0.4、0.6、0.8和1.0(重量%)的Pb-39Mg-10Al-1B-Y合金。使用X射线衍射,电子探针显微分析和扫描电子显微镜,极化曲线测试,电化学阻抗谱研究了Pb-39Mg-10Al-1B-Y合金在3.5 wt%NaCl溶液中的微观结构和电化学腐蚀行为。 (EIS)和电化学噪声(EN)。Mg 2 Pb + Pb共晶增益得到细化,Mg 17 Al 12的分布 通过添加Y,Mg的共晶增益变得连续。极化曲线,EIS结果和EN结果表明,各种Y浓度的合金的耐蚀性依次为0.8> 1> 0.6> 0.4> 0.2> 0。当Y≤0.4 wt。%和Y> 0.4 wt。%时,Pb-39Mg-10Al-1B-Y合金的主要腐蚀行为分别是一般腐蚀和局部腐蚀。存在一个Mg-Mg 2 Pb原电池,其中Mg 2 Pb作为阴极,Mg作为阳极。此外,氯-可以加速Mg相的腐蚀。

更新日期:2020-11-17
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