Catalysis Surveys from Asia ( IF 2.1 ) Pub Date : 2020-10-28 , DOI: 10.1007/s10563-020-09315-3 Sreedhar Gundekari , Sanjib Kumar Karmee
Depolymerisation of lignin produces concoction of aromatic compounds, such as, phenols, dihydroxybenzenes, alkylphenols, methoxyphenols, alkyl-methoxy substituted phenols, and diaryl ethers. This review presents an introduction on lignin, phenolic compounds and its value-added products, namely, cyclohexanols, cyclohexanones, and cyclohexanes obtained via hydrodeoxygenation/-hydrogenation reaction. The prior-art of catalytic interventions for selective preparation of cyclohexanols (a potential polymer and fuel intermediates) from lignin-based phenolic compounds are discussed. For this process, in-depth evaluation of nature of catalytic support, effect of reaction conditions (temperature and H2 pressure)/medium, active metallic sites, and mechanistic paths are performed.
中文翻译:
在负载型金属催化剂上用氢从木质素基酚和二芳基醚选择性合成环己醇中间体的评论
木质素的解聚产生芳族化合物的混合物,例如酚,二羟基苯,烷基酚,甲氧基酚,烷基-甲氧基取代的酚和二芳基醚。这篇综述介绍了木质素,酚类化合物及其增值产品,即通过加氢脱氧/加氢反应获得的环己醇,环己酮和环己烷。讨论了从木质素基酚类化合物选择性制备环己醇(潜在的聚合物和燃料中间体)的催化干预技术。对于该过程,进行了催化载体的性质,反应条件(温度和H 2压力)/介质,活性金属位点以及机械路径的影响的深入评估。