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Properties of Selenium Colloidal Solution Obtained via Laser Ablation and a Subsequent Method for Producing Highly Dispersed CuInSe2
JOM ( IF 2.6 ) Pub Date : 2020-10-19 , DOI: 10.1007/s11837-020-04407-x
S. V. Kochemirovskaia , D. V. Lebedev , A. A. Fogel , A. V. Povolotskiy , V. A. Kochemirovsky , Yu. S. Tver’yanovich

Various methods of synthesis of CuInSe2 remain relevant because it is one of the most effective materials for solar energy. An effective method for the preparation of the CuInSe2 nanodispersed selenium precursor for microwave synthesis is considered. Colloidal selenium solutions were obtained using laser ablation in various liquid media: water, ethanol, triethylene glycol, polyethylene glycol–400 (PEG-400), and a 1% solution of PEG-1500 in PEG-400. The optical properties of the obtained colloidal selenium solutions were studied. Electron microscopy of selenium particles was conducted. Trends of ablation rate change and physicochemical properties of dispersed selenium particles in the variety of liquid media listed above are discussed. The possibility of synthesizing CuInSe2 using the obtained precursor was verified.

中文翻译:

通过激光烧蚀获得的硒胶体溶液的特性以及随后用于生产高度分散的 CuInSe2 的方法

CuInSe2 的各种合成方法仍然适用,因为它是太阳能最有效的材料之一。考虑了一种制备用于微波合成的 CuInSe2 纳米分散硒前驱体的有效方法。在各种液体介质中使用激光烧蚀获得胶体硒溶液:水、乙醇、三甘醇、聚乙二醇-400 (PEG-400) 和 PEG-1500 在 PEG-400 中的 1% 溶液。研究了所得胶体硒溶液的光学性质。进行硒颗粒的电子显微镜检查。讨论了在上面列出的各种液体介质中分散的硒颗粒的烧蚀速率变化和物理化学性质的趋势。验证了使用获得的前体合成 CuInSe2 的可能性。
更新日期:2020-10-19
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