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Synthesis of Aminophenylpolycarbonitriles from Arylidenemalononitriles by the Michael Reaction
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-09-15 , DOI: 10.1134/s1070363220080289
M. A. Maryasov , V. V. Davydova , O. E. Nasakin , S. A. Shteingolts , O. A. Lodochnikova

Abstract

The reactions of arylidenemalononitriles with malononitrile, methyl cyanoacetate and cyanoacetamide yielded aminophenyldi- and tricarbonitriles. Formation of these compounds occurs through the dehydrocyanation step of the corresponding aminohexenepolycarbonitriles.



中文翻译:

迈克尔反应由丙烯基丙二腈合成氨基苯基聚碳酸酯

摘要

芳基丙二腈与丙二腈,氰基乙酸甲酯和氰基乙酰胺的反应产生了氨基苯基二腈和三腈。这些化合物的形成是通过相应的氨基己烯聚碳酸酯的脱氢氰化步骤进行的。

更新日期:2020-09-15
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