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Synthesis of Aminophenylpolycarbonitriles from Arylidenemalononitriles by the Michael Reaction

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Abstract

The reactions of arylidenemalononitriles with malononitrile, methyl cyanoacetate and cyanoacetamide yielded aminophenyldi- and tricarbonitriles. Formation of these compounds occurs through the dehydrocyanation step of the corresponding aminohexenepolycarbonitriles.

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Authors and Affiliations

  1. I.N. Ulyanov Chuvash State University, 428015, Cheboksary, Russia

    M. A. Maryasov, V. V. Davydova & O. E. Nasakin

  2. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 420088, Kazan, Russia

    S. A. Shteingolts & O. A. Lodochnikova

Authors
  1. M. A. Maryasov
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  2. V. V. Davydova
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  3. O. E. Nasakin
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  4. S. A. Shteingolts
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  5. O. A. Lodochnikova
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Correspondence to M. A. Maryasov.

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Maryasov, M.A., Davydova, V.V., Nasakin, O.E. et al. Synthesis of Aminophenylpolycarbonitriles from Arylidenemalononitriles by the Michael Reaction. Russ J Gen Chem 90, 1573–1577 (2020). https://doi.org/10.1134/S1070363220080289

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  • DOI: https://doi.org/10.1134/S1070363220080289

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