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Cation–Cation Interaction in Complexes of Np(V) Benzoate and Salicylate with N-Containing Molecular Ligands
Radiochemistry ( IF 0.9 ) Pub Date : 2020-03-23 , DOI: 10.1134/s1066362220010026 I. A. Charushnikova , N. N. Krot , V. P. Perminov
Radiochemistry ( IF 0.9 ) Pub Date : 2020-03-23 , DOI: 10.1134/s1066362220010026 I. A. Charushnikova , N. N. Krot , V. P. Perminov
The hydrothermal method was used to obtain two new compounds of Np(V): benzoate [(NpO2)3(py) (C7H5O2)3(H2O)2] (1) and salicylate [(NpO2)(phen)(HOC7H4O2)] (2), where py = pyridine and phen = 1,10-phenanthroline. An X-ray diffraction analysis of these compounds demonstrated that NpO+2 cations are bound together by cation-cation bonds to form distorted squared networks in compound 1 and zigzag chains in 2.
中文翻译:
Np(V)苯甲酸酯和水杨酸酯与含N分子配体的配合物中的阳离子间相互作用
使用水热法获得了两种新的Np(V)化合物:苯甲酸酯[(NpO 2)3(py)(C 7 H 5 O 2)3(H 2 O)2 ](1)和水杨酸盐[[NpO 2)(phen)(HOC 7 H 4 O 2)](2),其中py =吡啶,phen = 1,10-菲咯啉。该NPO这些化合物表现出的X射线衍射分析+ 2个阳离子通过阳离子阳离子键结合在一起,以形成扭曲平方网络在化合物1中和锯齿链2。
更新日期:2020-03-23
中文翻译:
Np(V)苯甲酸酯和水杨酸酯与含N分子配体的配合物中的阳离子间相互作用
使用水热法获得了两种新的Np(V)化合物:苯甲酸酯[(NpO 2)3(py)(C 7 H 5 O 2)3(H 2 O)2 ](1)和水杨酸盐[[NpO 2)(phen)(HOC 7 H 4 O 2)](2),其中py =吡啶,phen = 1,10-菲咯啉。该NPO这些化合物表现出的X射线衍射分析+ 2个阳离子通过阳离子阳离子键结合在一起,以形成扭曲平方网络在化合物1中和锯齿链2。