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Cation–Cation Interaction in Complexes of Np(V) Benzoate and Salicylate with N-Containing Molecular Ligands

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Abstract

The hydrothermal method was used to obtain two new compounds of Np(V): benzoate [(NpO2)3(py) (C7H5O2)3(H2O)2] (1) and salicylate [(NpO2)(phen)(HOC7H4O2)] (2), where py = pyridine and phen = 1,10-phenanthroline. An X-ray diffraction analysis of these compounds demonstrated that NpO+2 cations are bound together by cation-cation bonds to form distorted squared networks in compound 1 and zigzag chains in 2.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    I. A. Charushnikova, N. N. Krot & V. P. Perminov

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  1. I. A. Charushnikova
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  2. N. N. Krot
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  3. V. P. Perminov
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Correspondence to I. A. Charushnikova.

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Russian Text © The Author(s), 2020, published in Radiochemistry, 2020, Vol. 62, No. 1, pp. 11–19.

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Charushnikova, I.A., Krot, N.N. & Perminov, V.P. Cation–Cation Interaction in Complexes of Np(V) Benzoate and Salicylate with N-Containing Molecular Ligands. Radiochemistry 62, 9–17 (2020). https://doi.org/10.1134/S1066362220010026

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  • DOI: https://doi.org/10.1134/S1066362220010026

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