Formal Aerobic Oxidative Cross-Coupling of Benzofuranones with Azo Compounds Using Pd-μ-hydroxo Complex.,Chemical & Pharmaceutical Bulletin

当前位置： X-MOL 学术 › Chem. Pharm. Bull. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Formal Aerobic Oxidative Cross-Coupling of Benzofuranones with Azo Compounds Using Pd-μ-hydroxo Complex.
Chemical & Pharmaceutical Bulletin ( IF 1.5 ) Pub Date : 2020-09-01 , DOI: 10.1248/cpb.c20-00359
Rikako Ohnishi _{1,

2} , Masumi Sugawara ₁ , Tetsuya Ezawa ₃ , Yoshihiro Sohtome _{1,

3} , Mikiko Sodeoka _{1,

2,

3}

Affiliation

We have developed a catalytic aerobic oxidative dimerization reaction of benzofuranones using a Pd(II)-µ-hydroxo complex. Radical-radical cross-coupling of the resulting dimers with azo compounds enabled the one-pot synthesis of structurally congested benzofuranones having two distinct vicinal all-carbon quaternary centers.