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Attosecond spectroscopy of bio-chemically relevant molecules
La Rivista del Nuovo Cimento ( IF 5.9 ) Pub Date : 2018-07-23 , DOI: 10.1393/ncr/i2018-10150-2
F. Calegari, A. Trabattoni, E. Månsson, J. B. Greenwood, P. Decleva, F. Martìn, M. Nisoli

Understanding the role of the electron dynamics in the photochemistry of bio-chemically relevant molecules is key to getting access to the fundamental physical processes leading to damage, mutation and, more generally, to the alteration of the final biological functions. Sudden ionization of a large molecule has been proven to activate a sub-femtosecond charge flow throughout the molecular backbone, purely guided by electronic coherences, which could ultimately affect the photochemical response of the molecule at later times. We can follow this ultrafast charge flow in real time by exploiting the extreme time resolution provided by attosecond light sources. In this work recent advances in attosecond molecular physics are presented with particular focus on the investigation of bio-relevant molecules.

中文翻译:

生化相关分子的原子秒光谱

了解电子动力学在生物化学相关分子的光化学中的作用,是获得导致损坏,突变以及更普遍地导致最终生物学功能改变的基本物理过程的关键。大分子的突然电离已被证明可以激活整个分子主链上的飞秒级电荷流,这纯粹是由电子相干性引导的,这最终可能会在以后影响分子的光化学反应。通过利用阿秒光源提供的极限时间分辨率,我们可以实时跟踪超快电荷流。在这项工作中,提出了阿秒分子物理学的最新进展,特别着重于生物相关分子的研究。
更新日期:2018-07-23
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