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Condensation Product of p-anisaldehyde and L-phenylalanine: Fluorescent "on-off" Sensor for Cu2+ and IMPLICATION Logic Gate.
Journal of Fluorescence ( IF 2.6 ) Pub Date : 2020-08-24 , DOI: 10.1007/s10895-020-02600-4
Smita Sarma 1 , Bhaswati Devi 1 , Pradip Kr Bhattacharyya 2 , Diganta Kumar Das 1
Affiliation  

(Z)-2-(4-methoxybenzylideneamino)-3-phenylpropanoic acid (L) synthesized by condensation of p-anisaldehyde and L-phenylalanine acts as selective fluorescent as well as voltammetric sensor for Cu2+ in 2:1 (v/v) CH3OH:H2O. The fluorescence intensity of Lmax 425 nm) is quenched ca. 65% by Cu2+. Metal ions - Li+, Na+, K+, Al3+, Cu2+, Zn2+, Cd2+, Hg2+, Mn2+, Ni2+ and Pb2+ do not interfere. The binding constant and the detection limits were calculated to be 0.56 × 102 M−1 and 10−6 M respectively. DFT and TDDFT calculations confirmed 2:1 binding stoichiometry between L and Cu2+ obtained from fluorescence data. The interaction between L and Cu2+ is reversible for many cycles with respect to ethylenediamine tetraacetate anion (EDTA2−) which results in IMPLICATION logic gate.



中文翻译:

对茴香醛和L-苯丙氨酸的缩合产物:用于Cu2 +和IMPLICATION Logic Gate的荧光“开关”传感器。

对苯甲醛和L-苯丙氨酸缩合合成的(Z)-2-(4-甲氧基亚苄基氨基)-3-苯基丙酸(L)作为Cu 2+在2:1(v / v)CH 3 OH:H 2的O的荧光强度大号(λ最大425nm的)淬灭CA。Cu 2+占65%。金属离子-Li +,Na +,K +,Al 3+,Cu 2 +,Zn 2 +,Cd 2 +,Hg 2 +,Mn 2 +,Ni 2+和Pb 2+不干扰。结合常数和检测极限分别计算为0.56×10 2  M -1和10 -6M  。DFT和TDDFT计算证实了从荧光数据获得的L和Cu 2+之间的2:1结合化学计量。相对于乙二胺四乙酸根阴离子(EDTA 2-),L与Cu 2+之间的相互作用可逆多个循环,从而产生IMPLICATION逻辑门。

更新日期:2020-08-24
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