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Electrochemical detection of natural organic matter (humic acid) and splitting of hydrogen peroxide on a micropore 3D catalytic polysulfone–copper oxide nanocomposite surface
MRS Communications ( IF 1.9 ) Pub Date : 2020-09-01 , DOI: 10.1557/mrc.2020.61
Olayemi J. Fakayode , Thabo T.I. Nkambule

The development of new metalloplastic material from the combination of an alkaline-fused dehydrated glucose–copper (II) chloride, carbon soot, and polysulfone and the evaluation of its potential for the electrochemical detection of a pro-carcinogenic humic acid in water is reported. Excellent detection limit greater than 1 pico-part-per-million (order of 10–13 mg/L) was achieved, a value that proved to be first-of-its-kind till date. Transfer coefficients between 0.8 and 1.0 were realized. The new material showed some potential for splitting hydrogen peroxide to oxygen and thus may be explored for energy application in addition to its use as a water quality monitoring probe.

中文翻译:

天然有机物(腐植酸)的电化学检测和微孔 3D 催化聚砜-氧化铜纳米复合材料表面上过氧化氢的裂解

报告了由碱性熔融脱水葡萄糖 - 氯化铜 (II)、碳黑和聚砜组合开发的新型金属塑料材料,并评估了其电化学检测水中促癌腐植酸的潜力。实现了超过百万分之 1 微微分(10-13 毫克/升)的出色检测限,这一值迄今为止被证明是同类产品中的首创。实现了介于 0.8 和 1.0 之间的传递系数。这种新材料显示出一些将过氧化氢分解为氧气的潜力,因此除了用作水质监测探针外,还可以探索其能源应用。
更新日期:2020-09-01
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