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Thiophene-containing monomers for the synthesis of new polythiopheneferrocenes
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-06-01 , DOI: 10.1007/s11172-020-2881-9
E. N. Rodlovskaya , V. A. Vasnev

Synthesis of arylenebis(2-aminothiophene-3-carbonitriles) by the Gewald reaction was developed. The structures of the synthesized monomers were established by IR and NMR spectroscopy, mass spectrometry, and microanalysis. Polycondensation of these monomers with diacetylferrocene gave azomethine-bridged polythiopheneferrocenes.

中文翻译:

用于合成新型聚噻吩二茂铁的含噻吩单体

开发了通过 Gewald 反应合成亚芳基双(2-氨基噻吩-3-腈)的方法。通过红外光谱和核磁共振光谱、质谱和微量分析确定了合成单体的结构。这些单体与二乙酰二茂铁的缩聚得到偶氮甲碱桥连的聚噻吩二茂铁。
更新日期:2020-06-01
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