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Thiophene-containing monomers for the synthesis of new polythiopheneferrocenes

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Abstract

Synthesis of arylenebis(2-aminothiophene-3-carbonitriles) by the Gewald reaction was developed. The structures of the synthesized monomers were established by IR and NMR spectroscopy, mass spectrometry, and microanalysis. Polycondensation of these monomers with diacetylferrocene gave azomethine-bridged polythiopheneferrocenes.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    E. N. Rodlovskaya & V. A. Vasnev

Authors
  1. E. N. Rodlovskaya
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  2. V. A. Vasnev
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Correspondence to E. N. Rodlovskaya.

Additional information

NMR spectra were recorded and elemental analyses were performed using financial support from the Ministry of Science and Higher Education of the Russian Federation on the equipment of the Center for Molecule Composition Studies of INEOS RAS.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 18-03-00892).

On the occasion of the 65th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Based on the materials of the International Conference “Chemistry of Organoelement Compounds and Polymers 2019” (November 18–22, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1148–1150, June, 2020.

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Rodlovskaya, E.N., Vasnev, V.A. Thiophene-containing monomers for the synthesis of new polythiopheneferrocenes. Russ Chem Bull 69, 1148–1150 (2020). https://doi.org/10.1007/s11172-020-2881-9

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  • DOI: https://doi.org/10.1007/s11172-020-2881-9

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