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Effect of thermal annealing on crystal structure and properties of PLLA/PCL blend
Journal of Polymer Research ( IF 2.6 ) Pub Date : 2020-07-18 , DOI: 10.1007/s10965-020-02206-1
Jin Chen , Chengji Deng , Rui Hong , Qiang Fu , Jie Zhang

As far as we know, to enhance the toughness of poly(L-lactide) (PLLA) without compromising its inherent biodegradability, melt blending PLLA with flexible biodegradable polymers is the most effective and universal method. However, most of research results show a slight improvement in impact toughness due to the amorphous PLLA matrix. In other words, effective impact toughness can be achieved only if PLLA blend is in a highly crystalline state. In this work, blend of PLLA with 20 wt% PCL was prepared and then samples made by injection molding were applied to thermal annealing at different temperatures for 2 h to increase the crystallinity of PLLA matrix. The results show that the crystallinity of PLLA/PCL blend annealing at 80 °C is exceeding 40% and impact strength of the samples increases from 5.92 KJ/m2 of unannealed neat PLLA to 26.81 KJ/m2. At the same time, the thermal properties are also improved by a large margin.



中文翻译:

热退火对PLLA / PCL共混物晶体结构和性能的影响

据我们所知,要提高聚(L-丙交酯)(PLLA)的韧性而不损害其固有的生物降解性,将PLLA与柔性可生物降解的聚合物熔融共混是最有效和通用的方法。但是,大多数研究结果表明,由于非晶质PLLA基体的影响,冲击韧性略有提高。换句话说,仅当PLLA共混物处于高度结晶状态时,才能获得有效的冲击韧性。在这项工作中,制备了PLLA与20 wt%PCL的共混物​​,然后将通过注塑成型制成的样品在不同温度下进行热退火2小时,以提高PLLA基体的结晶度。结果表明,PLLA / PCL共混物在80°C退火时的结晶度超过40%,样品的冲击强度从5.92 KJ / m 2增加未退火的纯PLLA的最大拉伸强度为26.81 KJ / m 2。同时,热性能也大大提高。

更新日期:2020-07-20
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