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Synthesis and Characterization of Mn–Ce–VO x /TiO 2 Nanocomposite for SCR of NO x at Low Temperatures: Role of Mn, Ce and V Oxide
Topics in Catalysis ( IF 3.6 ) Pub Date : 2020-07-12 , DOI: 10.1007/s11244-020-01315-x
Jinxiu Wang , Xianfang Yi , Derrick Ng , Huirong Li , Jifa Miao , Qingfa Su , Jinsheng Chen , Zongli Xie

Mn–Ce–VOx/TiO2 (MnCeVTi), Mn–CeOx/TiO2 (MnCeTi) and Mn–VOx/TiO2 (MnVTi) nanocomposites as SCR DeNOx catalysts were synthesized by a modified sol–gel method. All catalysts shows high NOx conversion of over 90% at low temperature between 125 and 200 °C with GHSV of 30,000 h−1. MnCeVTi catalyst demonstrates the highest NOx conversion and produces the least byproduct N2O at 110–310 °C. The co-presence of Ce, V and Mn inhibits the growth of rutile, decreases crystallinity of anatase TiO2 and manganese oxides, reduces grain size, increases BET specific surface area and pore volume. There are most chemisorbed oxygen, appropriate Mn3+/Mn4+ and the synergistic effect of Ce and V on MnCeVTi sample. The acid sites on MnCeVTi are most below 280 °C and in widest temperature range. Lewis acid sites play a leading role in SCR reaction on MnCeVTi catalyst. These helps to optimize the SCR catalytic performance of MnCeVTi, on which E-R and L–H mechanism may coexist in the reaction.



中文翻译:

低温下用于NO x SCR的Mn–Ce–VO x / TiO 2纳米复合材料的合成与表征:Mn,Ce和V氧化物的作用

通过改进的溶胶-凝胶法合成了Mn-Ce-VO x / TiO 2(MnCeVTi),Mn-CeO x / TiO 2(MnCeTi)和Mn-VO x / TiO 2(MnVTi)纳米复合材料作为SCR DeNO x催化剂。所有的催化剂显示出高的NO X的90%的转化率在低温下125和200℃之间30000ħGHSV -1。MnCeVTi催化剂在110–310°C下表现出最高的NO x转化率和最少的副产物N 2 O。Ce,V和Mn的共存会抑制金红石的生长,降低锐钛矿型TiO 2的结晶度和锰氧化物,减小晶粒尺寸,增加BET比表面积和孔体积。化学吸附的氧最多,合适的Mn 3+ / Mn 4+以及Ce和V对MnCeVTi样品的协同作用。MnCeVTi上的酸位最低于280°C,且处于最宽的温度范围。路易斯酸位点在MnCeVTi催化剂的SCR反应中起主要作用。这些有助于优化MnCeVTi的SCR催化性能,在该催化性能上ER和L–H机理可能共存。

更新日期:2020-07-13
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