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Identification of Intercalates and Grafted Organic Derivatives of H 2 La 2 Ti 3 O 10 by Multinuclear NMR
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-20 , DOI: 10.1134/s1070363220040337
M. G. Shelyapina , I. P. Lushpinskaya , S. A. Kurnosenko , O. I. Silyukov , I. A. Zvereva

Abstract

Using 1H, 13C, and 15N NMR method, it was established that the formation of organic-inorganic hybrids of H2La2Ti3O10 with methylamine and butylamine produces intercalated alkylamino cations, while the introduction of methanol into the interlayer space of H2La2Ti3O10 is accompanied by the formation of covalent bonds.


中文翻译:

H 2 La 2 Ti 3 O 10的插层和接枝有机衍生物的多核NMR鉴定

摘要

使用1 H,13 C和15 N NMR方法,可以确定H 2 La 2 Ti 3 O 10与甲胺和丁胺的有机-无机杂化物的生成会产生嵌入的烷基氨基阳离子,同时将甲醇引入中间层H 2 La 2 Ti 3 O 10的空间伴随有共价键的形成。
更新日期:2020-06-20
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