Abstract

The conversion of alcohols into nitriles was studied under conditions of indirect electrochemical oxidation with a catalytic system 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl–potassium iodide–pyridine in a two-phase aqueous organic medium of methylene chloride–aqueous sodium hydrocarbonate (pH 8.6) in the presence of hydroxylamine as a source of nitrogen. The desired products were obtained with yields of up to 70%.

中文翻译：

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在电催化氧化条件下将醇转化为腈

摘要

在亚甲基两相有机水溶液中，在4-乙酰氨基-2,2,6,6-四甲基哌啶-1-氧基-碘化钾-吡啶催化体系间接电化学氧化条件下，研究了醇向腈的转化。氯化物–碳酸钠水溶液（pH 8.6）中存在羟胺作为氮源。获得所需产物，产率高达70％。