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Transformation of Alcohols into Nitriles under Electrocatalytic Oxidation Conditions
Russian Journal of Electrochemistry ( IF 1.1 ) Pub Date : 2020-06-12 , DOI: 10.1134/s1023193520050055
V. P. Kashparova , E. N. Shubina , I. B. Il’chibaeva , I. I. Kashparov , I. Yu. Zhukova , E. Sh. Kagan

Abstract

The conversion of alcohols into nitriles was studied under conditions of indirect electrochemical oxidation with a catalytic system 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl–potassium iodide–pyridine in a two-phase aqueous organic medium of methylene chloride–aqueous sodium hydrocarbonate (pH 8.6) in the presence of hydroxylamine as a source of nitrogen. The desired products were obtained with yields of up to 70%.



中文翻译:

在电催化氧化条件下将醇转化为腈

摘要

在亚甲基两相有机水溶液中,在4-乙酰氨基-2,2,6,6-四甲基哌啶-1-氧基-碘化钾-吡啶催化体系间接电化学氧化条件下,研究了醇向腈的转化。氯化物–碳酸钠水溶液(pH 8.6)中存在羟胺作为氮源。获得所需产物,产率高达70%。

更新日期:2020-06-12
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