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Polymerization shrinkage kinetics and degree of conversion of resin composites.
Journal of Oral Science ( IF 1.9 ) Pub Date : 2020-06-23 , DOI: 10.2334/josnusd.19-0157
Tong Xu 1 , Xuan Li 1 , Han Wang 1 , Gang Zheng 2 , Gaigai Yu 1 , Huimin Wang 1 , Song Zhu 1
Affiliation  

This study compared shrinkage strain, polymerization shrinkage kinetics, and degree of conversion (DC) of a set of resin composites and investigated their influencing factors. Ten commercial resin composites were assessed, and 5 specimens (n = 5) were developed for material and subjected to light curing using light emitting diode light at 650 mW/cm2 for 40 s. The laser triangulation method was adopted to assess the shrinkage strain, and Fourier transform infrared spectroscopy was used to measure DC. The shrinkage strain was monitored for 5 min in real time and its data were subjected to differential calculations to get the shrinkage strain rate curve with respect to time, obtaining the maximum shrinkage strain rate (Rmax) and gel time. The values of shrinkage strain varied from 1.28% to 2.10%. The Rmax values were between 5.17 μm/s and 21.83 μm/s. Gel time values varied from 3.08 s to 4.32 s. The DC yielded values ranging from 53.62% to 87.01%. The values of polymerization shrinkage and DC were dependent on the composition of materials, including the monomer matrix and filler system. Compared to the micro-filler materials, the nano-filler resin composites had higher values of DC. Some resin composites are suitable for clinical applications because of their superior polymerization shrinkage properties and DC.



中文翻译:

树脂复合材料的聚合收缩动力学和转化度。

这项研究比较了一组树脂复合材料的收缩应变,聚合收缩动力学和转化率(DC),并研究了其影响因素。评估了十种市售树脂复合材料,并开发了5个样品(n = 5)作为材料,并使用650 mW / cm 2的发光二极管光进行了40 s的光固化。采用激光三角测量法评估收缩应变,并使用傅立叶变换红外光谱法测量直流。实时监测收缩应变5分钟,对其数据进行微分计算,得出收缩应变率随时间变化的曲线,得出最大收缩应变率(R max)和凝胶时间。收缩应变的值在1.28%至2.10%之间变化。R max值在5.17μm/ s和21.83μm/ s之间。胶凝时间值从3.08 s到4.32 s不等。DC产生的值介于53.62%至87.01%之间。聚合收缩率和DC值取决于材料的组成,包括单体基质和填料体系。与微填料材料相比,纳米填料树脂复合材料具有更高的DC值。一些树脂复合材料因其优异的聚合收缩性能和DC而适合于临床应用。

更新日期:2020-08-23
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