Abstract

The heat capacity of cobalt trisdipivaloyl methanate Co(C₁₁H₁₉O₂)₃ was measured by the adiabatic method within the temperature range 8.18–301.61 K. The analysis of the functional dependence of the heat capacity did not revealed any thermal anomalies in its behavior. The thermodynamic functions (entropy, enthalpy, and reduced Gibbs energy) were calculated from the measured experimental data on the heat capacity within a temperature range of 0–300 K. The absolute entropy was used to calculate the formation entropy of Co(C₁₁H₁₉O₂)₃ at Т = 298.15 K.

中文翻译：

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三双新戊酰甲烷磺酸钴的低温热力学性质

摘要

通过绝热法在温度范围8.18-301.61 K下测量了_三二甲戊酰甲烷酸钴Co（C ₁₁ H ₁₉ O ₂）₃的热容量。对热容量的功能依赖性分析未发现其热容量异常。行为。根据在0–300 K温度范围内的热容量实测实验数据计算出热力学函数（熵，焓和降低的吉布斯能量）。使用绝对熵计算Co（C ₁₁ H）的形成熵。₁₉ O ₂）₃在Т = 298.15 K.