Abstract
The heat capacity of cobalt trisdipivaloyl methanate Co(C11H19O2)3 was measured by the adiabatic method within the temperature range 8.18–301.61 K. The analysis of the functional dependence of the heat capacity did not revealed any thermal anomalies in its behavior. The thermodynamic functions (entropy, enthalpy, and reduced Gibbs energy) were calculated from the measured experimental data on the heat capacity within a temperature range of 0–300 K. The absolute entropy was used to calculate the formation entropy of Co(C11H19O2)3 at Т = 298.15 K.
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This work was performed within the state assignment to the Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences in the field of fundamental scientific research.
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Chernyaikin, I.S., Bespyatov, M.A., Dorovskikh, S.I. et al. Low-Temperature Thermodynamic Properties of Cobalt Trisdipivaloyl Methanate. Russ. J. Inorg. Chem. 65, 650–654 (2020). https://doi.org/10.1134/S0036023620050058
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DOI: https://doi.org/10.1134/S0036023620050058