Abstract—МоO₂/С composites comprising monoclinic molybdenum dioxide were manufactured by microwave-assisted hydrothermal treatment of aqueous solutions of peroxomolybdic acid with glucose followed by annealing of the precursor in an inert atmosphere at 500°С. The carbon content in the composites ranged from 8 to 24 wt %. The major physicochemical characteristics of the compounds prepared were determined by X-ray powder diffraction, thermogravimetry, IR and Raman spectroscopy, scanning and electron microscopy, and low-temperature nitrogen adsorption. The molar component ratio of the reaction mass, Мо : С₆Н₁₂О₆ = 1 : (0.25–1.0), was found to be an essential factor that determined the composition, textural and thermal properties of МоО₂/С composites, as well as their formation specifics. A formation mechanism of МоО₂/С composites was suggested.

中文翻译：

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МоО2 /С复合材料：合成，性质和形成机理

摘要-МоO ₂ /С复合材料，其包括单斜晶系二氧化钼通过peroxomolybdic酸与葡萄糖的水溶液的微波辅助水热处理制造接着在500，在惰性气氛中的前体的退火°С。复合材料中的碳含量为8至24重量％。通过X射线粉末衍射，热重分析，IR和拉曼光谱，扫描和电子显微镜以及低温氮吸附来确定所制备化合物的主要理化特性。反应物质的摩尔成分比例，Мо：С ₆ Н ₁₂ О ₆= 1：（0.25-1.0），被发现是确定该组合物，МоО的质地性能和热性能的一个重要因素₂ /С复合材料，以及它们的形成细节。МоО的形成机构₂建议/С复合材料。