Abstract

The bis[(2E)-3-phenylprop-2-enoate]-tris(п-tolyl)antimony n-Tol₃Sb[OC(O)CH=CHPh]₂ complex is obtained as a result of interaction of tri-n-tolylantimony, hydrogen peroxide, and cinnamic acid. Its atomic structure is determined by X-ray diffraction (XRD) analysis. The crystals under investigation belong to the monoclinic system and have the following lattice parameters: sp. gr. \(P{{2}_{1}}{\text{/}}n\), Z = 4, a = 13.0480(2) Å, b = 12.3431(2) Å, c = 20.9868(3) Å, and β = 97.322(2)°. The antimony atom has a coordination corresponding to a distorted trigonal bipyramid. The composition and structure of the title compound are confirmed by IR spectroscopy and NMR spectroscopy.

中文翻译：

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新型有机化合物n -Tol 3 Sb [OC（O）CH = CHPh] 2的X射线衍射研究

抽象

的双[（2- ë）-3-苯基丙-2-烯酸乙酯] -三（п甲苯基）锑Ñ -Tol ₃的Sb [OC（O）CH = CHPh配合] ₂络合物作为相互作用的结果，得到三正甲苯磺酸，过氧化氢和肉桂酸。它的原子结构由X射线衍射（XRD）分析确定。被研究的晶体属于单斜晶系，并具有以下晶格参数：sp。gr。\（P {{2} _ {1}} {\ text {/}} n \），Z = 4，a = 13.0480（2）Å，b  = 12.3431（2）Å，c= 20.9868（3）Å，β= 97.322（2）°。锑原子具有对应于扭曲的三角双锥体的配位。通过IR光谱和NMR光谱确认标题化合物的组成和结构。