Skip to main content
SpringerLink
Log in

X-Ray Diffraction Study of New Organic Compound n-Tol3Sb[OC(O)CH=CHPh]2

  • STRUCTURE OF ORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The bis[(2E)-3-phenylprop-2-enoate]-tris(п-tolyl)antimony n-Tol3Sb[OC(O)CH=CHPh]2 complex is obtained as a result of interaction of tri-n-tolylantimony, hydrogen peroxide, and cinnamic acid. Its atomic structure is determined by X-ray diffraction (XRD) analysis. The crystals under investigation belong to the monoclinic system and have the following lattice parameters: sp. gr. \(P{{2}_{1}}{\text{/}}n\), Z = 4, a = 13.0480(2) Å, b = 12.3431(2) Å, c = 20.9868(3) Å, and β = 97.322(2)°. The antimony atom has a coordination corresponding to a distorted trigonal bipyramid. The composition and structure of the title compound are confirmed by IR spectroscopy and NMR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. C. Silvestru, I. Haiduc, R. T. Tiekink, et al., Appl. Organomet. Chem. 9 (7), 597 (1995).

    Article  Google Scholar 

  2. R. C. Liu, Y. Q. Ma, L. Yu, et al., Appl. Organomet. Chem. 17 (9), 662 (2003).

    Article  Google Scholar 

  3. G. C. Wang, J. Xiao, L. Yu, et al., J. Organomet. Chem. 689 (9), 1631 (2004).

    Article  Google Scholar 

  4. J. Mishra, A. Saxena, and S. Singh, Curr. Med. Chem. 14 (10), 1153 (2007).

    Article  Google Scholar 

  5. A. Islam, J. G. Da Silva, F. M. Berbet, et al., Molecules 19 (5), 6009 (2014).

    Article  Google Scholar 

  6. M. I. Ali, M. K. Rauf, A. Badshah, et al., Dalton Trans. 42 (48), 16733 (2013).

    Article  Google Scholar 

  7. V. V. Sharutin, O. K. Sharutina, A. P. Pakusina, et al., Russ. J. Coord. Chem. 29 (11), 780 (2003).

    Article  Google Scholar 

  8. V. A. Dodonov, A. V. Gushchin, Yu. L. Kuznetsova, and V. A. Morugova, Vestn. Nizhegorod. Univ., No. 1(4), 86 (2004).

  9. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

  10. CrysAlis CCD and CrysAlis RED (Rigaku Oxford Diffraction, 2015).

  11. L. J. Farrugia, J. Appl. Crystallogr. 32, 837 (1999).

    Article  Google Scholar 

  12. C. F. Macrae, P. R. Edgington, P. McCabe, et al., J. Appl. Crystallogr. 39, 453 (2006).

    Article  Google Scholar 

  13. A. L. Spek, Acta Crystallogr. D 65, 148 (2009).

    Article  Google Scholar 

  14. N. V. Somov and P. V. Andreev, Crystallogr. Rep. 63 (1), 32 (2018).

    Article  ADS  Google Scholar 

  15. L. Saleem, A. Ali, A. Badshah, et al., Inorg. Chim. Acta 474, 48 (2018).

    Article  Google Scholar 

  16. F. Asghar, A. Badshah, A. Shah, et al., J. Organomet. Chem. 717, 1 (2012).

    Article  Google Scholar 

  17. R. Mushtaq, M. K. Rauf, M. Bond, et al., Appl. Organomet. Chem. 30 (6), 465 (2016).

    Article  Google Scholar 

  18. T. Iftikhar, M. K. Rauf, S. Sarwar, et al., J. Organomet. Chem. 851, 89 (2017).

    Article  Google Scholar 

  19. S. Sarwar, T. Iftikhar, M. K. Rauf, et al., Inorg. Chim. Acta 476, 12 (2018).

    Article  Google Scholar 

  20. W. Qin, S. Yasuike, N. Kakusawa, and J. Kurita, J. Organomet. Chem., 693, 2949 (2008).

    Article  Google Scholar 

  21. V. V. Sharutin, O. K. Sharutina, A. P. Pakusina, et al., Russ. J. Coord. Chem. 29 (10), 694 (2003).

    Article  Google Scholar 

  22. S. S. Batsanov, Inorg. Mater. 37 (9), 871 (2001).

    Article  Google Scholar 

Download references

Funding

This study was performed within the basic part of State assignment for higher educational institutions and scientific organizations in the sphere of scientific activity, project no. 3.6502.2017/BCh.

Author information

Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, Russia

    A. L. Murgin, T. I. Ovsetsina, A. I. Maleeva, P. V. Andreev, N. V. Somov & A. V. Gushchin

Authors
  1. A. L. Murgin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. I. Ovsetsina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Maleeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Andreev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Somov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Gushchin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. I. Ovsetsina.

Additional information

Translated by Yu. Sin’kov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Murgin, A.L., Ovsetsina, T.I., Maleeva, A.I. et al. X-Ray Diffraction Study of New Organic Compound n-Tol3Sb[OC(O)CH=CHPh]2. Crystallogr. Rep. 65, 449–452 (2020). https://doi.org/10.1134/S1063774520030220

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774520030220

Search

Navigation