A novel decatungstate incorporated MOF of {[Cu(NPY)₂(H₂O)]₂(W₁₀O₃₂)}·2DMF·3H₂O (CuW–NPY; NPY = 3-amino-4,4′-bipyridine) has been synthesized by a diffusion method, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, diffuse reflectance spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. CuW–NPY represents a novel decatungstate-based MOF with 1D quadrilateral channels (9.1 Å × 5.6 Å) constructed from Cu–NPY square grids and [W₁₀O₃₂]⁴⁻ polyoxoanions via strong intermolecular hydrogen bonds and electrostatic interactions. Interestingly, CuW–NPY exhibits remarkable photocatalytic activities for the oxidation of cyclohexane to cyclohexanol and cyclohexanone with O₂ under visible-light irradiation. The successful synthesis of CuW–NPY not only enriches decatungstate-based hybrid materials, but also represents the advantages of the decatungstate incorporated MOF for the selective oxygenation of organic compounds by O₂.

{[Cu（NPY）₂（H ₂ O）] ₂（W ₁₀ O ₃₂）}·2DMF·3H ₂ O（CuW – NPY； NPY = 3-amino-4,4'-bipyridine ）已通过扩散法合成，并在结构上通过元素分析，红外光谱，紫外可见光谱，漫反射光谱，粉末X射线衍射（PXRD）和单晶X射线衍射进行了表征。CuW – NPY代表一种新颖的基于分解钨酸盐的MOF，具有由Cu–NPY正方形网格和[W ₁₀ O ₃₂ ] ⁴⁻构成的一维四边形通道（9.1Å×5.6Å）聚氧阴离子通过强大的分子间氢键和静电相互作用。有趣的是，CuW – NPY在可见光照射下对O ₂氧化环己烷生成环己醇和环己酮具有出色的光催化活性。CuW – NPY的成功合成不仅丰富了基于分解钨酸盐的杂化材料，而且代表了掺入分解钨酸盐的MOF的优势，可用于O ₂对有机化合物的选择性氧化。