Skip to main content
Log in

A Decatungstate Incorporated MOF for Visible-Light-Driven Photocatalytic Oxidation of Cyclohexane by Molecular Oxygen

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A novel decatungstate incorporated MOF of {[Cu(NPY)2(H2O)]2(W10O32)}·2DMF·3H2O (CuWNPY; NPY = 3-amino-4,4′-bipyridine) has been synthesized by a diffusion method, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, diffuse reflectance spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. CuWNPY represents a novel decatungstate-based MOF with 1D quadrilateral channels (9.1 Å × 5.6 Å) constructed from Cu–NPY square grids and [W10O32]4− polyoxoanions via strong intermolecular hydrogen bonds and electrostatic interactions. Interestingly, CuWNPY exhibits remarkable photocatalytic activities for the oxidation of cyclohexane to cyclohexanol and cyclohexanone with O2 under visible-light irradiation. The successful synthesis of CuWNPY not only enriches decatungstate-based hybrid materials, but also represents the advantages of the decatungstate incorporated MOF for the selective oxygenation of organic compounds by O2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Scheme 1

Similar content being viewed by others

References

  1. J.-C. Liu, Q. Han, L.-J. Chen, J.-W. Zhao, C. Streb, and Y.-F. Song (2018). Angew. Chem. Int. Ed. 57, 8416–8420.

    Article  CAS  Google Scholar 

  2. J.-W. Zhao, Y.-Z. Li, L.-J. Chen, and G.-Y. Yang (2016). Chem. Commun. 52, 4418–4445.

    Article  CAS  Google Scholar 

  3. Y. Guo, Y. Wang, C. Hu, Y. Wang, and E. Wang (2000). Chem. Mater. 12, 3501–3508.

    Article  CAS  Google Scholar 

  4. C. Chen, P. Lei, H. Ji, W. Ma, and J. Zhao (2004). Environ. Sci. Technol. 38, 329–337.

    Article  CAS  Google Scholar 

  5. J. He, Q. Han, J. Li, Z. Shi, X. Shi, and J. Niu (2019). J. Catal. 376, 161–167.

    Article  CAS  Google Scholar 

  6. D. Shi, R. Zheng, C.-S. Liu, D.-M. Chen, J. Zhao, and M. Du (2019). Inorg. Chem. 58, 7229–7235.

    Article  CAS  Google Scholar 

  7. Y. Zhang, J. Liu, S.-L. Li, Z.-M. Su, and Y.-Q. Lan (2019). EnergyChem 1, 100021.

    Article  Google Scholar 

  8. C. Cui, D. Shi, Z. Nie, L. Song, A. Ren, and C. Liu (2019). J. Clust. Sci.. https://doi.org/10.1007/s10876-019-01703-8.

    Article  Google Scholar 

  9. D. Shi, C. He, B. Qi, C. Chen, J. Niu, and C. Duan (2015). Chem. Sci. 6, 1035–1042.

    Article  CAS  Google Scholar 

  10. D.-Y. Du, J.-S. Qin, S.-L. Li, Z.-M. Su, and Y.-Q. Lan (2014). Chem. Soc. Rev. 43, 4615–4632.

    Article  CAS  Google Scholar 

  11. Q. Han, B. Qi, W. Ren, C. He, J. Niu, and C. Duan (2015). Nat. Commun. 6, 10007.

    Article  Google Scholar 

  12. D. Ravelli, D. Dondi, M. Fagnoni, and A. Albini (2009). Chem. Soc. Rev. 38, 1999–2011.

    Article  CAS  Google Scholar 

  13. A. Molinari, A. Maldotti, A. Bratovcic, and G. Magnacca (2013). Catal. Today 206, 46–52.

    Article  CAS  Google Scholar 

  14. I. Ryu, A. Tani, T. Fukuyama, D. Ravelli, M. Fagnoni, and A. Albini (2011). Angew. Chem. Int. Ed. 50, 1869–1872.

    Article  CAS  Google Scholar 

  15. C. Tanielian (1998). Coord. Chem. Rev. 178–180, 1165–1181.

    Article  Google Scholar 

  16. D. Shi, C. He, W. Sun, Z. Ming, C. Meng, and C. Duan (2016). Chem. Commun. 52, 4714–4717.

    Article  CAS  Google Scholar 

  17. M. D. Tzirakis, I. N. Lykakis, and M. Orfanopoulos (2009). Chem. Soc. Rev. 38, 2609–2621.

    Article  CAS  Google Scholar 

  18. A. Molinari, R. Amadelli, V. Carassiti, and A. Maldotti (2000). Eur. J. Inorg. Chem. 91–96.

  19. W. Wu, Z. Fu, S. Tang, S. Zou, X. Wen, Y. Meng, S. Sun, J. Deng, Y. Liu, and D. Yin (2015). Appl. Catal. B Environ. 164, 113–119.

    Article  CAS  Google Scholar 

  20. N. T. S. Phan, P. H. L. Vu, and T. T. Nguyen (2013). J. Catal. 306, 38–46.

    Article  CAS  Google Scholar 

  21. SMART Data collection software (version 5.629) (Bruker AXS Inc., Madison, 2003).

    Google Scholar 

  22. SAINT Data reduction software (version 6.45) (Bruker AXS Inc., Madison, 2003).

    Google Scholar 

  23. G. M. Sheldrick SHELX-97 (Program for crystal structure solution; University of Göttingen, Göttingen, 1997).

    Google Scholar 

  24. A. L. Spek PLATON99, A multipurpose crystallographic tool (Utrecht University, Utrecht, 1999).

    Google Scholar 

  25. D. Shi, L. Zeng, Z. Ming, C. He, C. Meng, and C. Duan (2016). RSC Adv. 6, 51936–51940.

    Article  CAS  Google Scholar 

  26. D.-Y. Shi, J.-W. Zhao, L.-J. Chen, P.-T. Ma, J.-P. Wang, and J.-Y. Niu (2012). CrystEngComm 14, 3108–3119.

    Article  CAS  Google Scholar 

  27. D. Shi, Z. Ming, Q. Wu, T. Lai, K. Zheng, C. He, and J. Zhao (2019). Inorg. Chem. Commun. 100, 125–128.

    Article  CAS  Google Scholar 

  28. D. Shi, C.-J. Cui, M. Hu, A.-H. Ren, L.-B. Song, C.-S. Liu, and M. Du (2019). J. Mater. Chem. C 7, 10211–10217.

    Article  CAS  Google Scholar 

  29. D. Shi, X. Guo, T. Lai, K. Zheng, Q. Wu, C. Sun, C. He, and J. Zhao (2019). Inorg. Chem. Commun. 105, 9–12.

    Article  CAS  Google Scholar 

  30. X. Xu, H. Li, S. Xie, L. Mei, R. Meng, L. Chen, and J. Zhao (2020). Inorg. Chem. 59, 648–660.

    Article  CAS  Google Scholar 

  31. D. Shi, C. Cui, H. Li, Z. Nie, and K. Zheng (2020). J. Light Ind. 35, 47–54.

    Google Scholar 

  32. I. Texier, J. A. Delaire, and C. Giannotti (2000). Phys. Chem. Chem. Phys. 2, 1205–1212.

    Article  CAS  Google Scholar 

  33. Y. Huang, L. Luo, J. Wang, Q. Zuo, Y. Yao, and W. Li (2015). J. Appl. Phys. 118, 044101.

    Article  Google Scholar 

  34. D. Shi, S. Shang, L. Chen, X. Cai, X. Wang, and J. Zhao (2012). Synth. Met. 162, 1030–1036.

    Article  CAS  Google Scholar 

  35. D. Shi, R. Zheng, M.-J. Sun, X. Cao, C.-X. Sun, C.-J. Cui, C.-S. Liu, J. Zhao, and M. Du (2017). Angew. Chem. Int. Ed. 56, 14637–14641.

    Article  CAS  Google Scholar 

  36. D. Ravelli, S. Protti, and M. Fagnoni (2016). Acc. Chem. Res. 49, 2232–2242.

    Article  CAS  Google Scholar 

  37. G. Laudadio, S. Govaerts, Y. Wang, D. Ravelli, H. F. Koolman, M. Fagnoni, S. W. Djuric, and T. Noël (2018). Angew. Chem. Int. Ed. 57, 4078–4082.

    Article  CAS  Google Scholar 

  38. A. Maldotti, A. Molinari, G. Varani, M. Lenarda, L. Storaro, F. Bigi, R. Maggi, A. Mazzacani, and G. Sartori (2002). J. Catal. 209, 210–216.

    Article  CAS  Google Scholar 

  39. A. Maldotti, A. Molinari, and F. Bigi (2008). J. Catal. 253, 312–317.

    Article  CAS  Google Scholar 

  40. A. Molinari, G. Varani, E. Polo, S. Vaccari, and A. Maldotti (2007). J. Mol. Catal. A Chem. 262, 156–163.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We are grateful to the support from the National Natural Science Foundation of China (21701147, 21805248), State Key Laboratory of Fine Chemicals (KF1701), Open Research Fund of Henan Key Laboratory of Polyoxometalate Chemistry (HNPOMKF1604), and the Startup Fund for Ph. D. of Natural Scientific Research of Zhengzhou University of Light Industry (2016BSJJ026).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Dongying Shi, Junping Du or Diming Chen.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shi, D., Wang, S., Cui, C. et al. A Decatungstate Incorporated MOF for Visible-Light-Driven Photocatalytic Oxidation of Cyclohexane by Molecular Oxygen. J Clust Sci 32, 579–584 (2021). https://doi.org/10.1007/s10876-020-01817-4

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-020-01817-4

Keywords

Navigation