Abstract
A novel decatungstate incorporated MOF of {[Cu(NPY)2(H2O)]2(W10O32)}·2DMF·3H2O (CuW–NPY; NPY = 3-amino-4,4′-bipyridine) has been synthesized by a diffusion method, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, diffuse reflectance spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. CuW–NPY represents a novel decatungstate-based MOF with 1D quadrilateral channels (9.1 Å × 5.6 Å) constructed from Cu–NPY square grids and [W10O32]4− polyoxoanions via strong intermolecular hydrogen bonds and electrostatic interactions. Interestingly, CuW–NPY exhibits remarkable photocatalytic activities for the oxidation of cyclohexane to cyclohexanol and cyclohexanone with O2 under visible-light irradiation. The successful synthesis of CuW–NPY not only enriches decatungstate-based hybrid materials, but also represents the advantages of the decatungstate incorporated MOF for the selective oxygenation of organic compounds by O2.
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Acknowledgments
We are grateful to the support from the National Natural Science Foundation of China (21701147, 21805248), State Key Laboratory of Fine Chemicals (KF1701), Open Research Fund of Henan Key Laboratory of Polyoxometalate Chemistry (HNPOMKF1604), and the Startup Fund for Ph. D. of Natural Scientific Research of Zhengzhou University of Light Industry (2016BSJJ026).
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Shi, D., Wang, S., Cui, C. et al. A Decatungstate Incorporated MOF for Visible-Light-Driven Photocatalytic Oxidation of Cyclohexane by Molecular Oxygen. J Clust Sci 32, 579–584 (2021). https://doi.org/10.1007/s10876-020-01817-4
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DOI: https://doi.org/10.1007/s10876-020-01817-4