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Gelatin-Based Nanobiocomposite Films as Sensitive Layers for Monitoring Relative Humidity in Food Packaging
Food and Bioprocess Technology ( IF 5.3 ) Pub Date : 2020-05-25 , DOI: 10.1007/s11947-020-02462-5
Pamela F. M. Pereira , Paulo H. S. Picciani , Veronica M. A. Calado , Renata V. Tonon

Gelatin-based nanocomposite films were prepared by casting and characterized as a sensitive hybrid material to relative humidity changes in the development of electrical sensors. Zinc oxide nanoparticles (ZnO-NPs) and glycerol (Gly) were incorporated as reinforcing and plasticizing agents, respectively, and their effects on the sensibility property of films were investigated. The proposed sensors were investigated at 25 °C. The behavior of gelatin-based films as a function of water presence was analyzed in terms of moisture content (MC), water vapor permeability (WVP), and water contact angle (WCA). The incorporation of ZnO-NPs and Gly induced morphological and structural changes in the composite films. Increased WCA (7.51%) and reduced WVP (18%) were observed for the nanocomposite films. In addition, ZnO-NPs and Gly significantly contributed to a further improvement of relative humidity sensibility of films compared to the control film. Electrical characterizations, carried out at different environments for gelatin-based films, revealed a positive responsive relative humidity behavior of materials and a sensibility of 99.47% for hybrid materials, suggesting the development of a new promising nanocomposite material for monitoring relative humidity conditions at 25 °C.



中文翻译:

基于明胶的纳米生物复合薄膜作为监测食品包装中相对湿度的敏感层

通过浇铸制备基于明胶的纳米复合薄膜,并将其表征为对电子传感器开发中相对湿度变化敏感的杂化材料。分别加入氧化锌纳米颗粒(ZnO-NPs)和甘油(Gly)作为补强剂和增塑剂,并研究了它们对薄膜敏感性的影响。建议的传感器在25°C下进行了研究。根据水分含量(MC),水蒸气渗透率(WVP)和水接触角(WCA)分析了基于明胶的薄膜的行为与水存在的关系。ZnO-NPs和Gly的引入引起复合膜的形态和结构变化。对于纳米复合膜,观察到WCA升高(7.51%)和WVP降低(18%)。此外,与对照膜相比,ZnO-NP和Gly大大有助于进一步改善膜的相对湿度敏感性。在不同环境下对明胶基薄膜进行的电学表征显示,材料的相对湿度行为具有正响应性,而杂化材料的灵敏度为99.47%,这表明开发了一种新的有前途的纳米复合材料来监测25°C的相对湿度条件C。

更新日期:2020-05-25
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