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Identification of Products of the Reactions of 2,2-Di(4-Nitrophenyl)-1-Chloroethene and 2,2-Di(4-Nitrophenyl)-1,1-Dichloroethene with Sodium Nitrite
Journal of Applied Spectroscopy ( IF 0.8 ) Pub Date : 2020-05-21 , DOI: 10.1007/s10812-020-00996-2
E. A. Guzov , V. N. Kazin , M. B. Kuzhin

Structures were established for the products of the reactions of 2,2-di(4-nitrophenyl)-1-chloroethene and 2,2-di(4-nitrophenyl)-1,1-dichloroethene with sodium nitrite and the ratio of these products was found using chemical balance, high-performance liquid chromatography, and IR spectroscopy data. The reaction of 2,2-di-(4-dinitrophenyl)-1-chloroethene with nitrite ion in dimethylformamide gives 50% 4,4'-dinitrobenzophenone, 30% 4,4'-dinitrobenzophenone oxime, and 20% 4,4'-dinitrobenzanilide. The products of the reaction of 2,2-di(4-nitrophenyl)-1,1-dichloroethene with NaNO2 in DMF gives 95–97% 4,4'-dinitrobenzophenone and 2.5–3.0% 4,4'-dinitrobenzophenone oxime.

中文翻译:

2,2-二(4-硝基苯基)-1-氯乙烯与2,2-二(4-硝基苯基)-1,1-二氯乙烯与亚硝酸钠反应的产物的鉴定

建立了2,2-二(4-硝基苯基)-1-氯乙烯和2,2-二(4-硝基苯基)-1,1-二氯乙烯与亚硝酸钠反应产物的结构以及这些产物的比例使用化学天平,高效液相色谱和红外光谱数据进行测定。2,2-二- (4-硝基苯基)-1-氯乙烯与亚硝酸根离子在二甲基甲酰胺反应,得到50%的4,4 -dinitrobenzophenone,30%4,4 -dinitrobenzophenone肟,和20%的4,4 ' -二硝基苯甲酰苯胺。2,2-二(4-硝基苯基)-1,1-二氯乙烯具有纳米的反应产物2在DMF中给出95-97%4,4 -dinitrobenzophenone和2.5-3.0%4,4 -dinitrobenzophenone肟。
更新日期:2020-05-21
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