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Identification of Products of the Reactions of 2,2-Di(4-Nitrophenyl)-1-Chloroethene and 2,2-Di(4-Nitrophenyl)-1,1-Dichloroethene with Sodium Nitrite

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Journal of Applied Spectroscopy Aims and scope

Structures were established for the products of the reactions of 2,2-di(4-nitrophenyl)-1-chloroethene and 2,2-di(4-nitrophenyl)-1,1-dichloroethene with sodium nitrite and the ratio of these products was found using chemical balance, high-performance liquid chromatography, and IR spectroscopy data. The reaction of 2,2-di-(4-dinitrophenyl)-1-chloroethene with nitrite ion in dimethylformamide gives 50% 4,4'-dinitrobenzophenone, 30% 4,4'-dinitrobenzophenone oxime, and 20% 4,4'-dinitrobenzanilide. The products of the reaction of 2,2-di(4-nitrophenyl)-1,1-dichloroethene with NaNO2 in DMF gives 95–97% 4,4'-dinitrobenzophenone and 2.5–3.0% 4,4'-dinitrobenzophenone oxime.

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Authors and Affiliations

  1. P. G. Demidov Yaroslavl State University, 150003, Yaroslavl, Russia

    E. A. Guzov, V. N. Kazin & M. B. Kuzhin

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  1. E. A. Guzov
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  2. V. N. Kazin
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  3. M. B. Kuzhin
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Correspondence to V. N. Kazin.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 2, pp. 261–267, March–April, 2020.

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Guzov, E.A., Kazin, V.N. & Kuzhin, M.B. Identification of Products of the Reactions of 2,2-Di(4-Nitrophenyl)-1-Chloroethene and 2,2-Di(4-Nitrophenyl)-1,1-Dichloroethene with Sodium Nitrite. J Appl Spectrosc 87, 275–281 (2020). https://doi.org/10.1007/s10812-020-00996-2

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  • DOI: https://doi.org/10.1007/s10812-020-00996-2

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