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Self-assembly of an organometallic Fe9O6 cluster from aerobic oxidation of (tmeda)Fe(CH2tBu)2.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-04-02 , DOI: 10.1039/d0cc00011f
Jonathan A Kephart 1 , Zachary Hecht , Brooke N Livesay , Indrani Bhowmick , Matthew P Shores , V Codrina Popescu , Navamoney Arulsamy , Elliott B Hulley
Affiliation  

Aerobic oxidation of (tmeda)Fe(CH2tBu)2 in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands. Mössbauer studies of the cluster are consistent with an all-ferrous assignment and magnetometry reveals complex intracluster and intercluster magnetic interactions.

中文翻译:

由(tmeda)Fe(CH2tBu)2的需氧氧化使有机金属Fe9O6团簇自组装。

(tmeda)Fe(CH2tBu)2在甲苯或THF溶液中的有氧氧化导致神奇大小的全氧化亚铁簇的自组装,该簇包含Fe9O6亚基并带有有机金属和二胺配体。Mössbauer对星团的研究与全铁元素的分配一致,磁力计揭示了复杂的星团内部和星群之间的磁性相互作用。
更新日期:2020-03-13
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