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Effect of Ce Doping on Hydrothermal Stability of Cu-SAPO-18 in the Selective Catalytic Reduction of NO with NH 3
Catalysis Surveys from Asia ( IF 2.1 ) Pub Date : 2020-02-27 , DOI: 10.1007/s10563-020-09294-5
Qi Gao , Qing Ye , Shuai Han , Shuiyuan Cheng , Tianfang Kang , Hongxing Dai

The Ce-Cu-SAPO-18 samples were prepared by the ion exchange method. Physicochemical properties of the samples were systematically characterized by a number of analytical techniques, and Ce doping and hydrothermal temperature effects on NH3-SCR activity of Cu-SAPO-18 were also investigated. The results show that doping of Ce increased NH3-SCR activity and hydrothermal stability of the Cu-SAPO-18 sample. After Ce doping, a more amount of the isolated Cu2+ ions entered the D6R and the catalyst structure was more stable. The structure and catalytic activity of Ce-Cu-SAPO-18 remained almost intact after hydrothermal aging at 650 °C. After hydrothermal aging at 850 °C, however, the structure of Ce-Cu-SAPO-18 was greatly destroyed, and its catalytic activity declined remarkably. The high-temperature hydrothermal aging treatment led to decreases in amount of the isolated Cu2+ ions and acidic sites, destroying in the zeolitic structure, and drop in NH3-SCR activity.



中文翻译:

Ce掺杂对NH 3选择性催化还原NO的作用对Cu-SAPO-18水热稳定性的影响

通过离子交换法制备了Ce-Cu-SAPO-18样品。通过多种分析技术系统地表征了样品的理化性质,并研究了Ce掺杂和水热温度对Cu-SAPO-18 NH 3 -SCR活性的影响。结果表明,Ce的掺杂增加了Cu-SAPO-18样品的NH 3 -SCR活性和水热稳定性。Ce掺杂后,更多的分离出的Cu 2+离子进入D6R,催化剂结构更加稳定。在650°C水热老化后,Ce-Cu-SAPO-18的结构和催化活性几乎保持不变。然而,在850°C水热老化后,Ce-Cu-SAPO-18的结构被大大破坏,其催化活性显着下降。高温水热老化处理导致分离的Cu 2+离子和酸性位点的数量减少,沸石结构破坏,并且NH 3 -SCR活性下降。

更新日期:2020-04-20
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