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Spiro indane-based phosphine–oxazoline ligands for palladium-catalyzed asymmetric arylation of cyclic N-sulfonyl imines
Transition Metal Chemistry ( IF 1.6 ) Pub Date : 2019-04-29 , DOI: 10.1007/s11243-019-00329-z Zhongxuan Qiu , Yanshun Li , Zhenqing Zhang , Dawei Teng
Transition Metal Chemistry ( IF 1.6 ) Pub Date : 2019-04-29 , DOI: 10.1007/s11243-019-00329-z Zhongxuan Qiu , Yanshun Li , Zhenqing Zhang , Dawei Teng
Palladium complexes of indane-based phosphine–oxazoline ligands with a spirocarbon stereogenic center were examined for asymmetric addition of arylboronic acids to cyclic N-sulfonyl imines. Excellent reaction activities (up to 99% yield) and enantioselectivities (up to 99% ee) were obtained with a broad scope of substrate.
中文翻译:
用于钯催化的环状 N-磺酰基亚胺不对称芳基化的螺茚基膦-恶唑啉配体
检查了基于茚满的膦-恶唑啉配体与螺碳立体中心的钯配合物,以检测芳基硼酸与环状 N-磺酰基亚胺的不对称加成。在广泛的底物范围内获得了优异的反应活性(高达 99% 的产率)和对映选择性(高达 99% ee)。
更新日期:2019-04-29
中文翻译:
用于钯催化的环状 N-磺酰基亚胺不对称芳基化的螺茚基膦-恶唑啉配体
检查了基于茚满的膦-恶唑啉配体与螺碳立体中心的钯配合物,以检测芳基硼酸与环状 N-磺酰基亚胺的不对称加成。在广泛的底物范围内获得了优异的反应活性(高达 99% 的产率)和对映选择性(高达 99% ee)。