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Spiro indane-based phosphine–oxazoline ligands for palladium-catalyzed asymmetric arylation of cyclic N-sulfonyl imines

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Abstract

Palladium complexes of indane-based phosphine–oxazoline ligands with a spirocarbon stereogenic center were examined for asymmetric addition of arylboronic acids to cyclic N-sulfonyl imines. Excellent reaction activities (up to 99% yield) and enantioselectivities (up to 99% ee) were obtained with a broad scope of substrate.

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Authors and Affiliations

  1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, 53 Zhengzhou Road, Qingdao, 266042, People’s Republic of China

    Zhongxuan Qiu, Yanshun Li, Zhenqing Zhang & Dawei Teng

Authors
  1. Zhongxuan Qiu
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  2. Yanshun Li
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  3. Zhenqing Zhang
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  4. Dawei Teng
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Correspondence to Dawei Teng.

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Qiu, Z., Li, Y., Zhang, Z. et al. Spiro indane-based phosphine–oxazoline ligands for palladium-catalyzed asymmetric arylation of cyclic N-sulfonyl imines. Transit Met Chem 44, 649–654 (2019). https://doi.org/10.1007/s11243-019-00329-z

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  • DOI: https://doi.org/10.1007/s11243-019-00329-z

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