A new potentially tridentate ligand 1,2,3-tris(isonicotinoyloxy)benzene (L) was prepared, and its coordination chemistry with various silver(I) salts AgX (X− = BF4−, ClO4−, PF6−, and CF3SO3−) was investigated in order to elucidate the effects of counteranion size. Self-assembly of silver(I) salts with L afforded four complexes with 1:1 stoichiometries. The molecular structures with small counteranions (BF4−, ClO4−, and PF6−) showed 2-D networks whereas those with large counteranions (CF3SO3−) showed a 1-D network. These silver(I) compounds were fully characterized by infrared spectroscopy, elemental and thermal analyses, and single crystal X-ray diffraction. The role of the present counteranions in determining the structural motifs is discussed in these pages.

中文翻译：

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含 1,2,3-三（异烟酰氧基）苯的银（I）配合物的构建和阴离子交换

制备了一种新的潜在三齿配体 1,2,3-三（异烟酰氧基）苯 (L)，并将其与各种银 (I) 盐 AgX（X− = BF4−、ClO4−、PF6− 和 CF3SO3−）进行配位化学反应) 进行了研究，以阐明抗衡阴离子大小的影响。银 (I) 盐与 L 的自组装提供了四种化学计量比为 1:1 的配合物。具有小抗衡阴离子（BF4-、ClO4- 和 PF6-）的分子结构显示二维网络，而具有大抗衡阴离子（CF3SO3-）的分子结构显示一维网络。这些银 (I) 化合物通过红外光谱、元素和热分析以及单晶 X 射线衍射进行了充分表征。这些页面中讨论了当前反阴离子在确定结构基序中的作用。