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Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review
Catalysis in Industry ( IF 0.7 ) Pub Date : 2019-05-17 , DOI: 10.1134/s2070050419010057
L. L. Gogin , D. Yu. Yushchenko , V. N. Konev , E. E. Sergeev , E. G. Zhizhina , T. B. Khlebnikova , Z. P. Pai

Abstract

Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids.


中文翻译:

二氯-[2,2]-环芳烷的合成方法:综述

摘要

描述了合成二氯-[2,2]-对环环烷(dichloroPCP)的方法,这是制造用于无线电电子的聚合物涂层的有价值的单体。俄罗斯目前没有用于生产的工厂。对考虑的合成方法的分析表明,霍夫曼消除季铵盐是工业生产dichloroPCP的最佳技术。在实践中进行该产物的四阶段合成的一种有前途的方式是使用诸如用碱和路易斯酸催化的催化技术。
更新日期:2019-05-17
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