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Rapid and green synthesis of 4H-benzo[b]pyrans using triethanolamine as an efficient homogeneous catalyst under ambient conditions
Research on Chemical Intermediates ( IF 2.8 ) Pub Date : 2020-01-10 , DOI: 10.1007/s11164-020-04081-3
Reyhaneh Rahnamafa , Leila Moradi , Mehdi Khoobi

4H-benzo[b]pyrans were obtained rapidly in high yields using triethanolamine as an efficient, eco-friendly and low-cost basic catalyst. One-pot three-component condensation reaction of a series of aldehydes, malononitrile and 1,3-diketones was performed at room temperature. All the products were obtained in high-to-excellent yields and characterized in detail. Green, rapid and mild process, very short reaction times (1–12 min) and simple workup are some of the advantages of this method.



中文翻译:

在环境条件下使用三乙醇胺作为有效的均相催化剂快速绿色合成4H-苯并[b]吡喃

使用三乙醇胺作为高效,环保和低成本的碱性催化剂,可以快速高产率地获得4H-苯并[b]吡喃。在室温下进行一系列醛,丙二腈和1,3-二酮的一锅三组分缩合反应。所有产品均以极高的出品率获得并进行了详细表征。绿色,快速,温和的过程,非常短的反应时间(1-12分钟)和简单的后处理是该方法的优点。

更新日期:2020-01-10
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